Composition by LC-MS/MS of New Carotenoid Esters in Mango and Citrus.
Identifieur interne : 000271 ( Main/Exploration ); précédent : 000270; suivant : 000272Composition by LC-MS/MS of New Carotenoid Esters in Mango and Citrus.
Auteurs : Fabiane C. Petry [Brésil] ; Adriana Z. Mercadante [Brésil]Source :
- Journal of agricultural and food chemistry [ 1520-5118 ] ; 2016.
Abstract
Interest in the composition of carotenoid esters of fruits is growing because esterification may affect their bioavailability. Thus, the aim was to provide a detailed identification of carotenoid esters in citrus and mango. Orange cv. 'Valencia' and cv. 'Pera' presented 9 free carotenoids, 38 monoesters, and 60 diesters. Violaxanthin and luteoxanthin derivatives were the major ones, followed by antheraxanthin, lutein, zeaxanthin, β-cryptoxanthin, and zeinoxanthin esters, many of them reported for the first time in orange pulp. The carotenoid ester composition of tangor cv. 'Murcott', reported for the first time, showed 8 free carotenoids, 34 monoesters, and 33 diesters, with β-cryptoxanthin esters as major compounds, followed by violaxanthin and zeaxanthin esters. In citrus, carotenoids were acylated mainly with capric, lauric, myristic, myristoleic, palmitic, palmitoleic, and oleic acids. In mango, 5 free carotenoids, 2 monoesters, and 19 diesters were identified, from which many violaxanthin and neoxanthin esters were reported for the first time.
DOI: 10.1021/acs.jafc.6b03226
PubMed: 27712060
Affiliations:
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Petry</name><affiliation wicri:level="2"><nlm:affiliation>Food Research Center (FoRC), Department of Food Science, Faculty of Food Engineering, University of Campinas (UNICAMP) , 13083-862 Campinas, SP, Brazil.</nlm:affiliation><country xml:lang="fr">Brésil</country><wicri:regionArea>Food Research Center (FoRC), Department of Food Science, Faculty of Food Engineering, University of Campinas (UNICAMP) , 13083-862 Campinas, SP</wicri:regionArea><placeName><region type="state">État de São Paulo</region></placeName></affiliation></author><author><name sortKey="Mercadante, Adriana Z" sort="Mercadante, Adriana Z" uniqKey="Mercadante A" first="Adriana Z" last="Mercadante">Adriana Z. Mercadante</name><affiliation wicri:level="2"><nlm:affiliation>Food Research Center (FoRC), Department of Food Science, Faculty of Food Engineering, University of Campinas (UNICAMP) , 13083-862 Campinas, SP, Brazil.</nlm:affiliation><country xml:lang="fr">Brésil</country><wicri:regionArea>Food Research Center (FoRC), Department of Food Science, Faculty of Food Engineering, University of Campinas (UNICAMP) , 13083-862 Campinas, SP</wicri:regionArea><placeName><region type="state">État de São Paulo</region></placeName></affiliation></author></analytic><series><title level="j">Journal of agricultural and food chemistry</title><idno type="eISSN">1520-5118</idno><imprint><date when="2016" type="published">2016</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Interest in the composition of carotenoid esters of fruits is growing because esterification may affect their bioavailability. Thus, the aim was to provide a detailed identification of carotenoid esters in citrus and mango. Orange cv. 'Valencia' and cv. 'Pera' presented 9 free carotenoids, 38 monoesters, and 60 diesters. Violaxanthin and luteoxanthin derivatives were the major ones, followed by antheraxanthin, lutein, zeaxanthin, β-cryptoxanthin, and zeinoxanthin esters, many of them reported for the first time in orange pulp. The carotenoid ester composition of tangor cv. 'Murcott', reported for the first time, showed 8 free carotenoids, 34 monoesters, and 33 diesters, with β-cryptoxanthin esters as major compounds, followed by violaxanthin and zeaxanthin esters. In citrus, carotenoids were acylated mainly with capric, lauric, myristic, myristoleic, palmitic, palmitoleic, and oleic acids. In mango, 5 free carotenoids, 2 monoesters, and 19 diesters were identified, from which many violaxanthin and neoxanthin esters were reported for the first time.</div></front></TEI><affiliations><list><country><li>Brésil</li></country><region><li>État de São Paulo</li></region></list><tree><country name="Brésil"><region name="État de São Paulo"><name sortKey="Petry, Fabiane C" sort="Petry, Fabiane C" uniqKey="Petry F" first="Fabiane C" last="Petry">Fabiane C. Petry</name></region><name sortKey="Mercadante, Adriana Z" sort="Mercadante, Adriana Z" uniqKey="Mercadante A" first="Adriana Z" last="Mercadante">Adriana Z. Mercadante</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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